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I have to agree. I refuse to buy any shirts, pants, tailoring, etc. that's made with synthetics. Socks, underwear, athletic gear, however, are horrible without it.There has been a long history here of people believing their clothes are made from natural fibers when, in fact, they are not. There was the famous Simonnot Godard chambray debacle. Will at ASW once wrote about another shirting that was "naturally wrinkle free." It was, in fact, a synthetic blend. There's a very esteemed knitwear maker that's often discussed on here. I interviewed the head of their company once about one of their more famous sweater styles. Although it's labeled as a pure natural fiber, it was in fact a synthetic blend.
There's an artist who, last year, had an exhibition at a Chicago museum. She took sample swatches from something like 100 "natural fiber" garments and had the fibers examined in a lab. I can't remember the percentage that came back as a synthetic blend, but it was shockingly high.
Think about it: how would an over-the-calf sock stay up your leg if it was made without synthetic? Cotton doesn't have a crimp. Wool fibers do, but can't be stretched and returned to that degree. Just because something is labeled as a natural fiber item does not make it so.