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I've never found any of Patagonia's socks to be dressy, though they're certainly thick.I found that NM/Barneys NY/etc carry cashmere (e.g. Brioni), merino, cotton (e.g. Zegna) that are quite thick.  High quality thick cashmere and merino are not hot in summer.  Boot socks tend to be thick but usually have too much heat holding synthetic  fiber--same with running/hiking/etc socks at REI.  And they are often rather ugly.  Maybe Padagonia/etc has some nice thick socks.
I find it works for me. But then again I am not talking about shoes that are one width too big, just shoes that are a little wider than I would like. The extra thickness of the socks is just enough to keep my feet from sliding around.Does anyone find that this method works? Â When I try to wear thicker socks to compensate for looser shoes, I find that my feet rub a lot and I get blisters.