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Originally Posted by
grouper 
I would actually caution against this if you're trying to get into ambient music... Selected Ambient Works 85-92, even though it is one of my favorite albums ever, the title is very misleading. The album is more of a compilation of "the lighter side" of Aphex Twin's work during that period (as opposed to I Care Because You Do), and it has a lot more techno aspects to it than does a traditional ambient record. Plus, I don't really find Selected Ambient Works II nearly as interesting.
No it's not very ambient, but it's not a bad stepping stone and it's a great album either way.
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All that stuff you mentioned about Pete Namlook (and anything involving the FAX label) is good stuff, though.
Yes, anything Namlook does is good, his music does span a wide spectrum though...
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Alva Noto's "Xerrox Vol. 2" might be good for starters, too. There's a lot of blending of digital elements of music (His other projects are more focused on digital composition and minimalist, austere electronics) and warmer, analog forms, like string samples. It's a pretty good and cohesive listen. Another artist that comes to mind when I think "accessible ambient" is Eluvium, who has branded himself quite successfully lately as an "emotional" ambient artist. This is sort of unfortunate as the origins of the genre lie in making music that can be focused on or regarded as background music with similar results - comparing Eluvium most recent material to Eno's early ambient work and "thinking music" is almost like comparing pop punk to first wave late 70s punk. That said, his early material is much better, notably "Talk Amongst The Trees."
If we're talking "accessible ambient" ala Brian Eno et.al, then Michael Stearns ("Planetary Unfolding") is very good, others to look into would be Erik Wøllo ("Elevations" and "Stream of Thought" with Steve Roach) and Jon Jenkins ("Beyond City Light"). Klaus Schulze, who is one of my favorites, is also very good, a lot of his earlier works ("Irrlicht") featured some samples and tape loops so they're fairly melodic. If you like Klaus' earlier stuff check out Neptune Towers (by Fenriz of Darkthrone) For some lesser known, but IMO spectacular, is the Finnish group Jääportit ("Uumenissa"). Also, since I'm listening to it now, I'll suggest Atomine Elektrine ("Archimetrical Universe"), it is heading more towards some darker ambient, but it's still quite melodic with some minor trance influences, it's not nearly as dark as the composer's other projects.